Adsorption Mechanism and Kinetic Characterization of Bituminous Coal under High Temperatures and Pressures in the Linxing-Shenfu Area     

TAO Chuanqi  WANG Yanbin  LI Yong  NI Xiaoming  GAO Xiangdong 《《地质学报》英文版》2020,94(2):399-408

The majority of coalbed methane(CBM) in coal reservoirs is in adsorption states in coal matrix pores. To reveal the adsorption behavior of bituminous coal under high-temperature and high-pressure conditions and to discuss the microscopic control mechanism affecting the adsorption characteristics, isothermal adsorption experiments under hightemperature and high-pressure conditions, low-temperature liquid nitrogen adsorption-desorption experiments and CO2 adsorption experiments were performed on coal samples. Results show that the adsorption capacity of coal is comprehensively controlled by the maximum vitrinite reflectance(Ro, max), as well as temperature and pressure conditions. As the vitrinite reflectance increases, the adsorption capacity of coal increases. At low pressures, the pressure has a significant effect on the positive effect of adsorption, but the effect of temperature is relatively weak. As the pressure increases, the effect of temperature on the negative effect of adsorption gradually becomes apparent, and the influence of pressure gradually decreases. Considering pore volumes of pores with diameters of 1.7-100 nm, the peak volume of pores with diameters 10-100 nm is higher than that from pores with diameters 1.7-10 nm, especially for pores with diameters of 40-60 nm, indicating that pores with diameters of 10-100 nm are the main contributors to the pore volume. The pore specific surface area shows multiple peaks, and the peak value appears for pore diameters of 2-3 nm, indicating that this pore diameter is the main contributor to the specific surface area. For pore diameters of 0.489-1.083 nm, the pore size distribution is bimodal, with peak values at 0.56-0.62 nm and 0.82-0.88 nm. The adsorption capability of the coal reservoir depends on the development degree of the supermicroporous specific surface area, because the supermicroporous pores are the main contributors to the specific pore area. Additionally, the adsorption space increases as the adsorption equilibrium pressure increases. Under the same pressure, as the maximum vitrinite reflectance increases, the adsorption space increases. In addition, the cumulative reduction in the surface free energy increases as the maximum vitrinite reflectance increases. Furthermore, as the pressure increases, the surface free energy of each pressure point gradually decreases, indicating that as the pressure increases, it is increasingly difficult to adsorb methane molecules.  相似文献   

The effects of simulated inundation duration and frequency on litter decomposition: A one-year experiment     

《Limnologica》2019

There is major uncertainty in the responses of litter decomposition to the inundation regimes in field studies, mainly because of the difficulties in identification of the individual effect of duration and frequency using field studies alone. The interactive role of inundation regime and litter quality also remains unclear. The responses of mass loss to simulated inundation regime (duration and frequency) and litter quality were investigated in leaves of Carex brevicuspis and leaves and stems of Miscanthus sacchariflorus from Dongting Lake, China. Three litter types differing in litter quality were incubated under seven different inundations over 360 days (three single inundations of 90, 180, and 360 days; three repeated 180-day inundations of 2, 3, and 6 times; and no inundations) in a pond near Dongting Lake. Initial N and P contents were highest in C. brevicuspis leaves, intermediate in M. sacchariflorus leaves, and lowest in M. sacchariflorus stems, whereas the organic C, cellulose, and lignin contents were ranked in the opposite order among the three litter types. Decomposition rate was highest in M. sacchariflorus leaves (0.00222–0.00900 day⁻¹), intermediate in C. brevicuspis leaves (0.00135–0.00500 day⁻¹), and lowest in M. sacchariflorus stems (0.00080–0.00100 day⁻¹). The decomposition rate of both C. brevicuspis and M. sacchariflorus leaves increased with increasing inundation duration or decreasing frequency. However, both duration and frequency of inundation had no effect on decomposition of M. sacchariflorus stems. At the end of the incubation, N mineralization was complete in leaf litters with increasing rates with increasing inundation duration or decreasing inundation frequency, but accumulation was found in M. sacchariflorus stems. Organic C decayed quickly in both leaf litters compared with the stem litter. These data indicate that inundation regime has no effect on the decomposition of refractory stem litter while prolonged and stable inundation stimulates the degradation of labile leaf litter.  相似文献   

轨道交通沿线土地溢价归公的政策与实践——以东莞市为例     

林雄斌  余筱琪  陈伟劲 《热带地理》2019,39(5):732-741

轨道交通周边土地开发和溢价归公有助于缓解城市财政压力,推动公交都市建设。结合国外实施溢价归公的政策和实践模式,以东莞市为例,在资料收集、政策分析、文本和案例解读的基础上,探讨了中国城市政府在规划和建设轨道交通中,以土地溢价归公反哺轨道交通融资的政策安排和实施效果。结果表明：1）溢价归公的本质是以特定方式实现正外部效应的内部化,由于土地制度和税收体系的差异,欧美地区溢价归公主要依赖多样化的土地税收体系,而中国城市的实践主要借鉴了“轨道+物业”的联合开发模式;2）东莞市溢价归公策略的形成是综合开发规划编制和审批、沿线土地控制和储备、土地发展权转移、土地增值分配等核心环节有效协调的结果;3）东莞轨道交通沿线土地开发能形成可观的财政收益,潜在土地收益占轨道资金总需求的比例超过20%,但在实施过程中仍面临较大困难。东莞市案例能为其他城市轨道交通融资、土地开发和溢价归公的政策体系编制和有效实施提供一定的参考。  相似文献   

Geochemical characteristics of a pre-Middle Jurassic oceanic crust fragment from the Central Pontides in northern Turkey: Geodynamic implications on intra-oceanic subduction initiation     

《Chemie der Erde / Geochemistry》2020,80(1):125535

The Central Pontides (northern Turkey) is one of the key localities to understand the geodynamic evolution of the Palaeo- and Neotethyan oceans. It consists of the pre-Jurassic basement units, the Early Jurassic and the Early Cretaceous accretionary complexes, the widespread Middle Jurassic continental arc magmatics and the Late Jurassic to Tertiary cover units. The Early Cretaceous accretionary complex is represented by the Central Pontide Structural Complex and includes the Middle Jurassic oceanic units, which were metamorphosed during the Early Cretaceous. Apart from these oceanic units, a few metaophiolite and serpentinite fragments have been recognized within the basement units, which may represent the remnants of an older ocean. The pre-Middle Jurassic Devrekani Metaophiolite is the largest oceanic fragment and tectonically intercalated within/between the Devrekani Metamorphics and the Çangaldağ Metamorphic Complex. It is mainly composed of harzburgites, dunites with chromite veins and metagabbros, and cut by metabasaltic andesites and metadacites. Petrographically, the gabbro consists mainly of plagioclase and clinopyroxene, and displays phaneritic/porphyritic texture. In contrast, the metabasaltic andesite includes plagioclase and mica phenocrysts within a fine-grained groundmass. Also, the metadacite is composed predominantly of quartz, plagioclase, and mica minerals. Two different magmatic groups belonging to completely different tectono-magmatic settings have been geochemically determined based on the immobile trace element systematics. The metadacites and metabasaltic andesites are akin to continental arc magmatics and characterized by negative Nb and Ta anomalies and depleted HFSE relative to Th and La contents. However, the metagabbro samples display the geochemical signatures of boninitic rocks and characterized by highly depletion in HFSEs and REEs relative to N-MORB. The Devrekani Metaophiolite in the Central Pontides may represent another remnant of pre-Middle Jurassic oceanic crust generation and can be north-eastward continuation of the Permian-aged Almacık complex and the Boğazköy Metaophiolite fragment in the western Sakarya Composite Terrane. It may have been cut by intrusions of the extensive Middle Jurassic continental arc magmatism after its imbrication within the basement unit. The presence of pre-Middle Jurassic oceanic units may indicate that the Paleozoic ocean may have survived as the Jurassic Intra-Pontide Ocean between the Scythian Platform and Sakarya Composite Terrane during the Mesozoic time. Thus, the Intra-Pontide Suture may normally include the Palaeozoic and Mesozoic remnants of the long-lived northward subducting Tethyan ocean.  相似文献   

Feedback control system for blow-out preventer positioning     

《Applied Ocean Research》2019

During the drilling of ultra-deep-water subsea petroleum wells, a blow-out preventer (BOP), a piece of safety equipment, must be assembled on the wellhead. The BOP is suspended using the drilling riser during the wellhead approach operation, and the riser's top end is connected to the floating platform rig. This article presents a feedback control system for the automatic approach of the BOP to the wellhead. Compared to state-of-the-art controls, ours does not require ancillary thrusters installed alongside the riser nor inclination sensors atop of the drilling riser. Additionally, our proposed control embeds a closed-loop dynamic positioning system, thus retaining the characteristics of the original control system and adding an extra closed-loop. This eases implementation of the BOP approach control to an existing platform. To calculate the optimal gains for the BOP controller, we assume a linear system for the riser, including only the pendulum-shape. The simulation is carried out using nonlinear models for both riser and floating platform. We assume an International Towing Tank Conference standard semi-submersible platform, coupled with a 3000-m free-hanging vertical riser for the time-domain simulation. The results show the BOP tracking to be a step-shaped input signal under current and wave loads. A discussion of the performance of feedback control under different environmental loads is also included.  相似文献   

基于ARIO模型的震后重建施工现场安全管理方法          下载免费PDF全文

顾连胜 《地震工程学报》2018,40(6):1350-1355

为提高受灾地区重建安全性，提出基于ARIO模型的震后重建施工现场安全管理方法。在将建筑设计影响因素划分为直接因素与间接因素的基础上，将ARIO模型引入震后重建施工现场安全管理中，利用其分析施工过程中各产业技术与该地区经济的联系，在考虑经济因素的基础上实现震后施工现场安全管理。设计并构建施工初期数据采集系统、施工前安全管理系统、施工过程中安全管理系统，将ARIO与VR结合，使各系统运行时施工人员能够在虚拟漫游中以第一视角完成虚拟施工，掌握整个工期、流程、所用设备等有关信息，并由辅助专家作出相应指导，实现震后重建施工现场安全系统化管理。提出施工安全辅助建议，以完善灾后重建安全管理方法。实验结果表明，该方法运行后安全系数大于当前方法，其科学性和鲁棒性较强。  相似文献   

One-step solution to local tie vector determination at co-located GNSS/VLBI sites     

Xiaping Ma  Kegen Yu  Jean-Philippe Montillet  Xiaoxing He 《Studia Geophysica et Geodaetica》2018,62(4):535-561

The local tie vector, which connects the different space geodetic techniques at a co-located site, plays an important role in the realization of the International Terrestrial Reference Frame (ITRF). This paper presents a new method to determine the tie vector between the GNSS and very long baseline interferometry tracking points. The parameters of the local tie vector and the axes offsets are introduced into constraint equations. The parameters are then resolved using the 3D constrained least squares adjustment. With the surveying data collected at two different sites (Kunming and Urumqi) in China, the proposed method can precisely determine the local tie vectors in a geocentric frame. The root mean square error (RMSE) is (1.2, 2.3 and 1.5 mm) and (1.0, 1.5 and 1.4 mm) for the three coordinate components at the sites in Kunming and Urumqi, respectively. The offset between the primary and secondary axes of the VLBI telescopes is estimated to be 7.5 mm in Kunming’s site and 4.0 mm in Urumqi’s site, and the corresponding RMSE is 1.8 mm and 2.0 mm for the two sites, respectively.  相似文献   

全干涉成像的微地震定位方法研究   总被引：1，自引：0，他引：1       下载免费PDF全文

田宵  张雄  张华  麻昌英  戴梦雪  储仿东 《地球物理学报》2020,63(8):3105-3115

基于偏移成像的微地震定位方法由于可避免走时拾取误差以及可实现自动化定位等优点被广泛应用.绕射叠加方法将能量沿走时曲线聚焦到空间网格点上,进行成像时需要搜索发震时刻.干涉成像方法利用互相关提取的走时差信息可避免搜索发震时刻,但定位结果受数据信噪比的影响较大.为了进一步提高干涉成像法的定位精度,本文提出一种同时使用互相关和自相关道集的全干涉成像方法,增加的自相关道集提取的S-P走时差可降低震源-检波器方向的定位误差,提高定位精度.单井监测的理论测试和实际数据的研究结果表明,全干涉成像的定位精度高于仅使用互相关道集的干涉成像方法,同时计算效率高于绕射叠加方法.  相似文献   

长江口局域时空流场构建及实时流量精确估计     

陈志高 《测绘学报》2020,49(6):802-802

正长江三角洲是我国经济发达、人口密集的地区之一,其丰富的水资源对经济发展作用巨大。获取该水域准确的时空流场及实时流量信息,对于水利工程规划建设、防洪减灾及水资源科学管理和合理分配等意义重大。受河道、径流潮流、变化流速等因素综合影响,长江口水域流速直接获取困难、流场组成不单一、流量实时准确估计困难,严重影响了该水域流场及流量信息的准确获取及其应用。据此,开展了长江口局域时空流场构建及实时流量精确估计方法研究。论文的主要内容如下。  相似文献   

结合PS特征点的SBAS地表形变监测     

聂运菊  熊佳诚  程朋根  罗跃 《测绘通报》2020,(4):91-95

针对SARscape SBAS技术存在人工选取地面控制点影响监测结果的问题，本文提出了一种结合PS特征点的SBAS地表形变监测方法。通过设置PS技术中的振幅离差指数与相干性阈值，提取PS监测结果中的特征点作为地面控制点进行轨道精炼与形变反演。以2017年3月至2018年12月覆盖南昌地区的Sentinel-1影像为数据源，进行了地表形变监测与验证。结果表明：①该方法与PS方法监测结果均显示南昌市城区在监测时段内整体呈小幅度上升趋势，年平均沉降速率相关性达到了0.959，具有高度一致性。②将该方法、PS方法、人工选取地面控制点的SBAS方法的监测结果与水准数据进行对比，该方法与水准数据的误差不超过3.5 mm，说明了该方法的有效性。  相似文献